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At the very close of the 19th century, German chemist Hans von Pechmann noted a precipitate while working with a form of methane in ether. In 1900, German chemists Eugen Bamberger and Friedrich Tschirner identified this compound as polymethylene, a very close cousin to polyethylene. Thirty years later, a high-density residue was created by an American chemist at E.I. du Pont de Nemours & Company, Inc., Carl Shipp Marvel, by subjecting ethylene to a large amount of pressure. Working with ethylen.

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