If you are considering resigning from the DOE, we strongly suggest contacting the union at 212-331-6311 to speak with a representative about your options. The term "voluntary separation" as used in the statute means leaving employment of one's own free will.Reason for Resignation: INSTRUCTIONS. Employee–Complete Section I and forward to your supervisor. A verbal resignation is unacceptable. How to write a resignation letter that's effective immediately? It's time to quit the job, and you're not giving two weeks' notice. Here's how to politely write a resignation letter, effective immediately. These resignation letter templates would help you write yours in no time, and learn how generative AI can help too. Click below for up-to-date forms and documents for use in submitting address or name changes, W4 forms for adjusting withholding status when needed.