Exemption applications must be filed with your local assessor's office. See our Municipal Profiles for your local assessor's mailing address.Search tax forms and instructions. The taxpayer must declare the exemption using personal property form 102 or 103. Wayne County Tax Claim Bureau conducts Tax Sales under the general provisions of The Pennsylvania Real Estate Tax Sale Law Act 542 of 1947 and its Amendments. Pay your delinquent property taxes online through our quick and secure payment website. As a convenience, two electronic payment options are available. The Assessor's Office is responsible for estimating the value of your property, expressed as its taxable or assessed value. Do I need to file a Personal Property Statement for my business? Yes, State law mandates that a Personal Property Tax Statement be completed annually.