Can you purchase a money order with these cards? Many of the cards have ATM access where you can get cash and deposit to your account but this one does not.Most places don't allow customers to buy money orders with gift cards. Thankfully, there are a few places that accept gift cards, but there are restrictions. At one of my Walmarts, no gebit cards will work for money orders. At my regular, go to Walmart, it has been up and down in terms of what works. - At Food Lion I have used 8 cards for just under 3k in MOs. Yes, at the Money Center, or customer service. They can be purchased with cash, or debit card. By Mail: Check from a US bank (also cannot be a temporary check); Cashier's Check; Money Order.