In many cases, charitable donations are tax-deductible. When you donate to a qualifying organization, you can deduct the amount from your taxable income.Enter the entity name and identifying number from the tax return where the noncash charitable contribution was originally reported, if different from above. Only donations made to a qualified charity can be deducted. Do you need a donation receipt letter to claim a tax deduction? Form 990-PF - Provide a copy of the Form 990-PF. Include the nonprofit's EIN so the the donor can to check the charity's tax-exempt status with the IRS. To qualify for federal tax-exempt status from the IRS, Form 1023 must be completed and filed with the Internal Revenue Service. How to deduct your Goodwill donations on your taxes. Complete this form to request your donation tax receipt.