Generally, you can only deduct charitable contributions if you itemize deductions on Schedule A (Form 1040), Itemized Deductions. Bystep guide on how to fill out a Goodwill tax donation receipt.This form is available at our stores in Maine, New Hampshire and Vermont. Can you use a donation receipt template? How do I submit a donation request? Please fill out our material donation form. Donation Valuation Guide. Learn about the value of your Salvation Army donation with per item valuation in our handy guide. Donate. Would you like to make a donation. The receipt serves as proof of the donation and provides the information necessary for the donor to claim a tax deduction.