Completed applications should be sent to Virginia Tax, Nonprofit Exemption Unit, P. O. Box 715, Richmond, Virginia 23218-0715, or faxed to 804.786.2645. Enter the entity name and identifying number from the tax return where the noncash charitable contribution was originally reported, if different from above.Your organization may not solicit in the. Commonwealth of Virginia until it is properly registered. 1. As mentioned above, to claim a charitable donation, you need to itemize your deductions using Form 1040, Schedule A as part of your tax preparation. Your donations to Goodwill – whether goods or money – are tax deductible. Goodwill is an IRS-approved 501(c)(3) nonprofit organization.