In this blog post, we'll walk you through the typical steps of the escrow process and what homeowners can expect when selling a home in Phoenix. Title and escrow process for sales in Maricopa, Pinal, and Pima County.Escrow process occur once both buyer and seller had accepted an offer and agreed on all the terms and conditions. Typically, you have 10 days to do all of your inspections and investigations of the home. You can inspect anything to do with the home. How The Arizona Escrow Process Works. The escrow process starts in Arizona when the purchase contract between the buyer and seller is finalized. Rely on the escrow experts at Arizona Escrow for personal property escrow closings across Arizona and nationwide. In a real estate transaction, the Buyer does not pay the Seller directly for the property. Any party to the real estate transaction may open escrow as soon as the Purchase Contract is fully executed.