Once your donation is successfully completed, we will send you an email donation receipt as your official record. The Donation Value Guide below helps you determine the approximate tax-deductible value of some of the more commonly donated items.A Salvation Army donation receipt is used to report items at cash value when determining the tax-deductible value. Step 1: Enter your zip code in the "schedule a pick-up" box on our home page. You will be directed to the donation details page for your local donation center. A donation receipt will be sent to you at the email address you provide on this form. Please be sure to keep a copy of your receipt for tax purposes. Don't forget your email address. How to fill out the Donation Form for The Salvation Army? 1. Collect your personal details. 2.