Your financial donations to The Salvation Army help us serve the most vulnerable members of your community. The Donation Value Guide below helps you determine the approximate tax-deductible value of some of the more commonly donated items.When you donate goods to The Salvation Army, all donation proceeds are used to fund our Adult Rehabilitation Centers. Click here to learn more! 333 N. 44th St. Suite 100, Phoenix, AZ 85008. 100 Club of Arizona. 22541. Now you can create your own digital donation receipt from the salvation army. You'll never have to scramble again to find your paper receipts. The Salvation Army Donation Center. This is called "out of area care.