Goodwill will provide a receipt as substantiation for your contributions in good used condition, only on the donation date. There are many other reasons to send a receipt after receiving a donation.To apply for exemption, submit Form AP-205, Texas Application for Exemption – Charitable Organizations (PDF), to the Comptroller's office. Enter the entity name and identifying number from the tax return where the noncash charitable contribution was originally reported, if different from above. We're making it easier than ever for you to trace your Goodwill donation receipts for tax purposes. There is no official IRS form that the exempt organization has to complete. Questions about federal tax-exempt status? Contact the IRS Exempt Organizations Section at 877-829-5500. If you have a question about a specific donation you've made, please fill out our donor inquiry form. Be sure to distribute these receipts in a timely manner so donors can file their tax returns on time.