Understand what a charitable donation is and how to claim a tax deduction without a tax receipt with IRS Form 8283. You cannot claim a charitable contribution without a receipt.Accurately track and value items you donate to charities with ItsDeductible™ plus other donations such as cash, mileage, and stocks with our free, easy app. Goodwill will provide a receipt as substantiation for your contributions in good used condition, only on the donation date. If you would like to make a tax-deductible charitable donation, you may do so in a number of ways. How can I give online? Generally, you can only deduct charitable contributions if you itemize deductions on Schedule A (Form 1040), Itemized Deductions. To apply for exemption, submit Form AP-205, Texas Application for Exemption – Charitable Organizations (PDF), to the Comptroller's office. When you donate, the DGR will usually issue you with a receipt, but they don't have to. Caring for infants to adolescents, Cincinnati Children's Hospital Medical Center is an international leader in pediatric medicine, research and education.