Get a free Pennsylvania LLC Operating Agreement (Word, PDF, or Google Doc) to customize for your LLC. List LLC Members, tax info, and more.Free operating agreement template for single member LLCs. Free sample operating agreement template you can complete in minutes. To form an LLC, a Certificate of Organization is required to be filed with the Corporation Bureau of the. That's why we created a comprehensive, easy-to-use operating agreement template. Learn about forming and registering your business online, and how to complete other types of business filings. Register your business (opens in a new tab). A Pennsylvania single-member LLC operating agreement outlines the rules and framework of a limited liability company (LLC) that has one sole owner. You can use one of our attorney-drafted templates to fill out, save, and download your operating agreement for free.