Arizona residents who qualify, complete this form to request to have no Arizona income tax withheld from their wages. The department created exemption certificates to document non-taxable transactions.This establishes a basis for state and city tax deductions or exemptions. Arizona Form 5000 is used to claim Arizona TPT (sales tax) exemptions from a vendor. The purpose of the certificate is to document tax-exempt transactions with qualified purchasers. Certificate is to document and establish a basis for state and city tax deductions or exemptions. These vehicle license tax exemptions are available at the time of application for an Arizona title and registration. For information or help, call one of the numbers listed: Phoenix. Submit copies of: First 2 pages of Arizona Tax Return Form 140, including any Nontaxable strike benefits, for all household members for 2024, if applicable. As of January 5, 2021, Form 1024A applications for recognition of exemption must also be submitted electronically online at Pay.gov.