Use our Form Filler to fill out your form and print it. For the best experience, use a desktop or laptop computer.Go to our Online Passport Appointment System. You may apply at the following post offices: Williamsburg Post Office 425 N Boundary Street Williamsburg, VA 23185. By appointment only. The City of Chesapeake processes passport applications for those who need to apply for a new passport. Appointment Required. Applications are accepted a.m. At an acceptance facility,; By mail,; At a passport agency or center, or; Online (eligible renewal customers only). Passport applications are accepted Monday - Friday, excluding holidays, during normal office hours ( AM - PM).